Yes. However, this is only possible when the panel or Z-Wave lock's PIN code is managed through a Personal Access Plan.
When using a standard Access Plan to manage multiple users, panel and Z-Wave pin codes cannot be scheduled and will allow 24/7 access. This occurs regardless of what the standard Access Plan schedule says due to scheduling incompatibilities between Z-Wave locks, panels, and Access Control doors.
For more information about personal access plans, see What is a Personal Access Plan?.